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Apparent molar property : ウィキペディア英語版
Apparent molar property
An apparent molar property is an intensive quantity associated with a component of a solution that is back-computed from the corresponding property of the whole solution via a mole-weighted sum. For instance, the volume of a single-solute solution can be written as
: V=V_0 + _ n_ + _ its molar volume (at the same temperature and pressure as the solution), n0 is the number of moles of solvent, ^\phi\tilde_1\,. The first term is equal to the volume of the same quantity of solvent with no solute, and the second term is the change of volume on addition of the solute. ^\phi\tilde_1\, is described only as an ''apparent'' value.
Conversely, if we take the molar volume \tilde_1 of the solvent as the starting point, the apparent molar volume of the solvent can be defined via:
: V= n_ + \tilde_1 n_1 \,
which emphasizes the change of the volume of the solvent in the mixing process.
Also the apparent quantities can be expressed using mass. This expression produces apparent specific quantities, like the apparent specific volume.
: V=V_0 + ^\phi_1 m_1 \,
where the specific quantities are denoted with small letters.
Apparent (molar) properties are not constants (even at a given temperature), but are functions of the composition. At infinite dilution, an apparent molar property and the corresponding partial molar property become equal.
Some apparent molar properties that are commonly used are apparent molar enthalpy, apparent molar heat capacity, and apparent molar volume.
==Relation to molality==
The apparent (molar) volume of a solute can be expressed as a function of the molality b of that solute (and density of the solution and solvent):
: ( \frac - \frac) + \frac
For multicomponent systems the relation is slightly modified by the sum of molalities of solutes.
: ( \frac - \frac) + \frac

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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